Search for: All records

Abstract We investigate the properties and relationship between Doppler velocity fluctuations and intensity fluctuations in the off-limb quiet Sun corona. These are expected to reflect the properties of Alfvénic and compressive waves, respectively. The data come from the Coronal Multichannel Polarimeter (COMP). These data were studied using spectral methods to estimate the power spectra, amplitudes, perpendicular correlation lengths, phases, trajectories, dispersion relations, and propagation speeds of both types of fluctuations. We find that most velocity fluctuations are due to Alfvénic waves but that intensity fluctuations come from a variety of sources, likely including fast and slow mode waves, as well as aperiodic variations. The relation between the velocity and intensity fluctuations differs depending on the underlying coronal structure. On short closed loops, the velocity and intensity fluctuations have similar power spectra and speeds. In contrast, on longer nearly radial trajectories, the velocity and intensity fluctuations have different power spectra, with the velocity fluctuations propagating at much faster speeds than the intensity fluctuations. Considering the temperature sensitivity of COMP, these longer structures are more likely to be closed fields lines of the quiet Sun rather than cooler open field lines. That is, we find the character of the interactions of Alfvénic waves and density fluctuations depends on the length of the magnetic loop on which they are traveling. 

Abstract Large Stokes shift (LSS) red fluorescent proteins (RFPs) are highly desirable for bioimaging advances. The RFP mKeima, with coexistingcis‐andtrans‐isomers, holds significance as an archetypal system for LSS emission due to excited‐state proton transfer (ESPT), yet the mechanisms remain elusive. We implemented femtosecond stimulated Raman spectroscopy (FSRS) and various time‐resolved electronic spectroscopies, aided by quantum calculations, to dissect thecis‐ andtrans‐mKeima photocycle from ESPT, isomerization, to ground‐state proton transfer in solution. This work manifests the power of FSRS with global analysis to resolve Raman fingerprints of intermediate states. Importantly, the deprotonatedtrans‐isomer governs LSS emission at 620 nm, while the deprotonatedcis‐isomer's 520 nm emission is weak due to an ultrafastcis‐to‐transisomerization. Complementary spectroscopic techniques as a table‐top toolset are thus essential to study photochemistry in physiological environments.